Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst.
摘要：
[reaction: see text] The Rh-TangPhos catalyst has been used for asymmetric hydrogenation of itaconic acid and enol acetate derivatives. A variety of chiral 2-substituted succinic acids and chiral acetates have been obtained in excellent ee values (up to 99% ee).
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关键词：
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism reduction, hydrogenation carboxylic acids (acyclic compounds carboxylic acids (benzene compounds carboxylic acids (naphthalene compounds catalysis, phase‐transfer catalysis
DOI：
10.1021/ol0272592
被引量：
年份：
2003
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