Statistical Thermodynamics of Solutions of Optically Active Substances. I. Excess Free Energy of Binary Solution of d- and l-Isomers
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16
摘要:
A statistical mechanical theory of solutions consisting of d- and l-optical isomers is developed based on a new model of optically active molecules, and the excess free energy of the system is also derived and the order of magnitude of this quantity is examined.
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DOI:
10.1246/bcsj.34.1689
被引量:
年份:
2006
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