Removal of toluene-p-sulphonyl groups from sulphonamides. Part 4. Synthesis of phenylglyoxal imine monomers
摘要:
Syntheses and reactions of N-tosylphenacylamines with bases have been systematically examined. Monomeric C-methoxy-imines are available from some of these reactions. C-methoxyphenacylarylamines, made by two routes, were converted into monomeric imines on treatment with noble-metal catalysts. The boron trifluoridecatalysed reactions of aryl aldehydes with sulphonamides provide a new and convenient route to N-sulphonylarylimines.
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DOI:
10.1039/P19810002435
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年份:
1981
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2006
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