Thermodynamic properties of chiral fenchones in some solutions at T = 298.15 K
摘要：
Excess enthalpies for binary mixtures ( S-fenchone + ethanol/benzene/cyclohexane/carbon tetrachloride) were measured over the whole concentration at T = 298.15 K. The experimental results were compared with the values obtained from the UNIFAC, COSMO-RS and regular solution theory. Excess enthalpies of binary mixtures of R-fenchone and S-fenchone in ethanol, benzene, and cyclohexane solution at different specified mole fractions of fenchone have been measured under the same conditions. With the decreasing of the specified mole fraction of fenchone in different solutions, the excess enthalpies of mixing of chiral orientated solutions increased and became close to zero. Results were compared with those of chiral limonene in ethanol solution. Pair interaction energies were also investigated.
展开
DOI：
10.1016/j.jct.2010.12.004
被引量：
年份：
2011
Elsevier
Elsevier
(全网免费下载)
国家科技图书文献中心
(权威机构)
掌桥科研
dx.doi.org
查看更多
Ingenta
ResearchGate
EBSCO
cheric.org
onAcademic
en.zl50.com
Elsevier
(全网免费下载)
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
