Regioselective and Stereospecific Cross‐Coupling of Primary Allylic Amines with Boronic Acids and Boronates through Palladium‐Catalyzed C?N Bond Cleavage
摘要：
The NH2group serves as an effective leaving group in the palladium-catalyzed regioselective and stereospecific title reaction (see scheme). The reaction works well with aryl- and alkenylboronic acids and aryl-, alkenyl-, allyl-, and benzylboronates, and complete transfer of chirality has been achieved when using -chiral primary allylic amines as the allylic electrophiles.
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关键词：
allylic compounds C<IMG alt=[BOND] src="http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif">N bond cleavage cross-coupling boron palladium
DOI：
10.1002/anie.201109171
被引量：
年份：
2012
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