Stereoselective synthesis of (η6-arene)chromium complexes possessing chiral amine and hydroxy groups: chiral ligands in asymmetric synthesis
摘要:
Stereoisomeric optically active (η6-di-substituted arene)chromium complexes possessing amino and hydroxyl groups at the both benzylic positions have been synthesized with high selectivity. These chiral (arene)chromium complexes catalyze an asymmetric ethylation of benzaldehyde with diethylzinc.
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DOI:
10.1016/0040-4039(91)80041-4
被引量:
年份:
1991
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