Oxygenation of a Ruthenium Complex Bearing a PBP-Pincer Ligand Inducing the Formation of a Boronato Ligand with a Weak Ru–O Bond
摘要：
A ruthenium hydride complex having a boron-containing PBP pincer ligand was synthesized. Oxygenation of this complex by using NMO formed the corresponding boronate complex with a nearly 90 degrees B-O-Ru angle and a long Ru-O bond. A detailed structural and theoretical study revealed B=O double-bond character and a very small contribution of a p pi-d pi interaction between Ru and O.
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关键词：
TRANSITION-METAL-COMPLEXES BORYLENE COMPLEXES COORDINATION BORYLLITHIUM IMINOBORANES REACTIVITY AMINO-9-FLUORENYLIDENEBORANE CHEMISTRY PLATINUM DICOBALT
DOI：
10.1021/om400915x
被引量：
年份：
2013
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