Asymmetric allylation of aromatic aldehydes catalyzed by chiral phosphoramides prepared from (S)-proline - ScienceDirect
摘要：
Chiral phosphoramides prepared from (S)-proline were used to catalyze the allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes in good enantioselective yields. Phosphoramides 4d and 4m gave chiral homoallylic alcohols and their enantiomers, respectively, with similar levels of enantioselectivity.
展开
关键词：
alcohols (acyclic compounds stereochemistry (general, optical resolution alkylation, arylation, dealkylation, dearylation, C‐acylation, olefination
DOI：
10.1016/S0040-4020(97)00084-7
被引量：
年份：
1997
相似文献
参考文献
引证文献
辅助模式
0
引用
文献可以批量引用啦~
欢迎点我试用！
