Thermal electron transfer reactions in polar solvents
摘要：
A quantum mechanical theory of electron transfer reactions is developed using the techniques employed in solid-state and radiationless transition theory. This theory allows one to incorporate the effects of both the long-range polaron modes of the liquid and the short-range specific hydrational modes around the ions. Typical calculations suggest that the resulting temperature dependence of the activation energy may be observed experimentally in some cases.
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DOI：
10.1021/j100614a017
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年份：
1974
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来源期刊
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1993
被引量：53
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