Sunlight photooxidation of isobutylene and butene-1 with NO2 in low- and high-oxygen concentrations
摘要：
Sunlight photooxidations at ppm levels of butene-1 and of isobutylene with NO 2 were made in air and in atmospheres with less than 200 ppm oxygen. This work was undertaken to observe differences in the products in photooxidations with low- and high-oxygen concentrations. In the low-oxygen atmosphere the products were characterized by oxygen atom-olefin reactions. In the air the products were characteristic of ozone-olefin reactions. The photooxidations were faster in the low-oxygen atmosphere than in air.
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关键词：
environmental sciences butenes photochemistry nitrogen dioxide smog photochemical oxidants alkenes oxygen chalcogenides chemistry
DOI：
10.1016/0004-6981(71)90163-6
被引量：
年份：
1971
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