Resonance enhanced two-photon ionization studies in a supersonic molecular beam: Bromobenzene and iodobenzene
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43
摘要：
The1B2(ππ*)←1A1absorptions of two monosubstituted halobenzenes have been investigated using resonance enhanced two‐photon ionization in a pulsed supersonic molecular beam. Detection of the photoions was accomplished by means of a time‐of‐flight mass spectrometer. The1B2←1A1system of bromobenzene has been observed with good sensitivity using this technique, even though the total decay rate of the1B2state is greater than 1×1011sec1. No ion signal was observed when the same transition was probed in iodobenzene, allowing us to place a lower limit on its decay rate of 4×1013sec1.
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DOI：
10.1063/1.440000
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年份：
1980
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来源期刊
Chemischer Informationsdienst
19801115
引用走势
1982
被引量：20
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