The first triazatrimethylenemethane dianion: crystal structure of dilithio-triphenylguanidine Li2[C(NPh)3] as its tetrahydrofuran solvate
摘要：
The dilithiation of N,N′,N″-triphenylguanidine with n-butyllithium in tetrahydrofuran provides the first example of a triazatrimethylenemethane system [C(NPh)3]2–, isoelectronic with both [C(CH2)3]2– and [CO3]2–; the X-ray crystal structure of the dilithium salt shows it to exist as a dimer with planar CN3 structural units.
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关键词：
GUANIDINIUM CHLOROANTIMONATE PHASE TRANSITION DSC DILATOMETRIC PYROELECTRIC ELECTRIC CONDUCTIVITY
DOI：
10.1039/c39950001647
被引量：
年份：
1995
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