Gas phase inorganic synthesis: copper sulfide cluster anions react withphosphorus, P4, to generate copper compounds withPmSn ligands
摘要:
Anions [Cu xS y] - reactedwith P 4 (g) to form products which were formally addition ofP 2 units, but are shown by density functional calculationsand collisional induced dissociation to containP nS m ligands co-ordinated to copper; thereactivities of the [Cu xS y] - ionscorrelate with their geometrical rather than electronic structures,according to the principles which are described.
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DOI:
10.1039/A703341I
被引量:
年份:
1997
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来源期刊
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1999
被引量:4
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