The effect of weak chelating agents on the removal of heavy metals by precipitation processes
摘要:
Particle size distributions and heavy metal removals are presented for hydroxide precipitations and heavy metal removals are presented for hydroxide precipitation and sulfide precipitation of zinc and cadmium in the presence of several weak complexing agents, namely citrate, tartrate, and ammonia. The pH was held constant at pH 10.0 in these experiments. The presence of these weak complexing agents had little effect on the chemical equilibrium for both the hydroxide and sulfide systems due to their weak complexing ability with metal ions. The presence of the complexing agents does affect the particle size distribution, generally forming smaller particles. Particle size distributions are presented for the Zn(OH)<sub>2</sub>, ZnS, Cd(OH)<sub>2</sub>, and CdS systems (at pH 10.0) in the presence of the chelating agents citrate, tartrate, and ammonia. Sulfide precipitation exhibits a better particle size distribution and settling characteristics than the corresponding metal hydroxide preci
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DOI:
10.1002/ep.670050307
被引量:
年份:
1986
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