Ring-construction/stereoselective functionalization cascade: total synthesis of pachastrissamine (jaspine B) through palladium-catalyzed bis-cyclization of bromoallenes.
摘要:
In the presence of Pd(PPh3)4, substrates (I) and (V) undergo bis-cyclization to give furooxazole derivatives.
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关键词:
furan derivatives ring closure reactions diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism) oxazole derivatives lipids
DOI:
10.1002/chin.201041094
被引量:
年份:
2010
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来源期刊
Journal of Organic Chemistry
2010/11/29 0:00:00
引用走势
2011
被引量:49
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