ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a Chem...
some more aspects of catalysis viz.; use of different metal complexes as homogeneous catalyst towards the dihydrogen reduction of various organic substrates. ...
some more aspects of catalysis viz.; use of different metal complexes as homogeneous catalyst towards the dihydrogen reduction of various organic substrates. ...
Getting heavy: At temperatures as low as 50°C, D2O can serve as a cheap and readily available deuterium source for the efficient deuteration of aromatic a...
Catalytic dehydrogenation of methanol proceeded with homogeneous ruthenium(II) complexes, yielding formaldehyde and dihydrogen as primary products under re...
Catalytic activity of homogeneous and heterogeneous rhodium complexes with polyethyleneimine or ethylenediamine at various Rh:N ratios has been studied in ...
In conventional chemistry, dihydrogen typically plays the role of a reductant and a reagent for homogeneous and heterogeneous hydrogenation processes such as ...
Earth-abundant manganese bipyridine complexes have been extensively studied as homogeneous electrocatalysts for proton-coupled CO2 reduction. To date, these manganese complexes have not been examined as catalysts for the reduction of oth...
The first σ complexes were found in the 1960s and 1970s, but they did not attract more than passing attention. Only now are we beginning to recognize thei...
Nonlinear systems can not be totally determined by the conjugate pairs of through and across variables routinely used in nonequilibrium thermodynamics and ...
Tris(triphenylphosphine)chlororhodium(I), RhCl(PPh3)3, has been prepared by the interaction of an excess of triphenylphosphine with rhodium(III) chloride hydrate in ethanol; the corresponding bromide and iodide are also described. The di...
The dicationic Os(II) complex [Os(bpy)(PPh(3))(2)(CO)(H(2))](2+) has been prepared as the triflate salt. The presence of a bound dihydrogen ligand is indic...
Asymmetric hydrogenation reactions can provide practical access to a diverse array of chiral building blocks. We have developed a variety of highly selecti...
Neutron diffraction structure determinations of transition metal hydrides have been reviewed. Molecular complexes as well as solid state compounds are surv...
Oligosaccharides were extracted from tissues and body fluids of five kittens with alpha-mannosidosis, three being from the same litter. The kittens were al...
RuH(Ph)(CO)L2 (L = PtBu2Me) reacts with SiH2Ph2 to give first benzene and RuH(SiHPh2)(CO)L2, and then RuH3(SiHPh2)(CO)L2 and Ru(H)2(CO)L2, the trihydride b...
Complexes in which a -HE bond (E=H, B, Si, C) acts as a two-electron donor to the metal center are called complexes. Clues that it is possible to intercon...
ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInformof ...
Under mechanical milling conditions, direct reductive benzylizations of malononitrile and 4-methylaniline by aromatic aldehydes were achieved using a Hantz...
Transition metal TM hydrides display a remarkable range of bonding types, encompassing classical M–H moieties, dihydrogen complexes containing the η2-H2l...
The investigation of the 52 largest Austrian rivers with catchment areas > 500 km(2) (Danube River excluded) provides a national estimate of the ecological...
The cyclopentadienyl complex Os(η5-C5H5)Cl(PiPr3)2 (1) reacts with molecular hydrogen to give a mixture of the isomers transoid-dihydride OsH2(η5-C5H5)Cl...
Treatment of cis-[W(N2)2(PMe2Ph)4] (5) with an equilibrium mixture of trans-[RuCl(eta 2-H2)(dppp)2]X (3) with pKa = 4.4 and [RuCl(dppp)2]X (4) [X = PF6, BF...
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a Chem...
