Synthesis of optically active forms of ipsdienol and ipsenol
摘要：
( R )-(-)-Ipsdienol 1 ″ and its antipode 1 ' were synthesized from (R)-(+)-glyceraldehyde acetonide and ( R )-(+)-malic acid, respectively. This established the S-configuration of the naturally occurring (+)-ipsdienol. A new synthesis of ( R )-(+)-ipsenol 2 ″ and its antipode 2 ' was also described. Chiral epoxides were shown to be useful intermediates for the synthesis of these chiral alcohols.
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DOI：
10.1016/S0040-4020(01)93705-6
被引量：
年份：
1979
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