First regio- and enantioselective chromium-catalyzed homoallenylation of aldehydes.
摘要：
Serving up an ace! The first regio- and enantioselective version of a chromium-catalyzed homoallenylation of an aldehyde is described by P.J. Guiry and co-workers in their Communication on page9152ff. The non-C2-symmetric bis(oxazoline) ligand (tennis racket) interacts with the Crdiene complex (ball), which approaches the aldehyde (net) from the Reface to afford valuable chiral -allenols. The Crhomoallene complex remains out of the game!
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DOI：
10.1002/anie.200905607
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年份：
2010
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来源期刊
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2011
被引量：36
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