Synthesis and Crystal Structure of [NBu4]2[Pt24(CO)48]: An Infinite 1D Stack of {Pt3(CO)6} Units Morphologically Resembling a CO‐Insulated Platinum Cable
摘要：
Pieces of eight: Upon crystallization, [NBu4]2[Pt24(CO)48] self‐assembles into infinite one‐dimensional stacks of {Pt3(CO)6} units arranged in layers separated by [NBu4]+ ions. Close examination of the {Pt3(CO)6} stacks, which resemble CO‐insulated platinum cables (see picture; CO ligands omitted), shows them to be composed of alternating blocks of seven {Pt3(CO)6} units and single {Pt3(CO)6} units.
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DOI：
10.1002/anie.200503495
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年份：
2005
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