Magnetism, electronic spectra, and structure of transition metal alkoxides. V. Copper(II) methoxides
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27
摘要:
Najor differences in magnetism are observed in the series CuXL where X = -OMe, Cl, Br, and L = -OMe, acac. Cu(OMe), exhibits linear antiferro- magnetism, CuCl(OMe) follows the Curie law with μeff 2.0 B.M., and CuBr(OMe) is only feebly paramagnetic. The magnetism of Cu(OMe) acac may be interpreted in terms of a singlet-triplet equilibrium with -J = 725 cm-1 (2.08 kcal mole-1).
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DOI:
10.1071/CH9672351
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年份:
1967

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