Mechanistic Insights into Cu-Catalyzed Asymmetric Aldol Reactions: Chemical and Spectroscopic Evidence for a Metalloenolate Intermediate
摘要：
In situ IR spectroscopy and transmetalation experiments confirm a postulated catalytic cycle. The metalloenolate 1 describes the active intermediate in the aldol reaction catalyzed by [CuF<sub>2</sub>{(S)-tol-binap}] (see reaction scheme). (S)-tol-binap=(S)-(−)-2,2′-bis(di-p-tolylphosphanyl)-1,1′-binaphthyl.
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DOI：
10.1002/(SICI)1521-3773(19981204)37:22<3124::AID-ANIE3124>
被引量：
年份：
1998
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