Synthesis of 1,1-Diborylalkenes through a Br?nsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
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17
摘要：
A method for the synthesis of 1,1-diborylalkenes through a Brønsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles.
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DOI：
10.1002/anie.201509218
年份：
2015
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