摘要：

Pd^II‐catalyzed Michael reactions of β‐dicarbonyl compounds 1 and enones 2 can generate quaternary stereocenters (shown in yellow) with selectivities of 90?% ee at relatively high temperatures (?10?°C). This method represents a breakthrough in enantioselective synthesis. <img class="figure__image" src="https://wol-prod-cdn.literatumonline.com/cms/attachment/9164c204-c94a-4917-b13a-55687aa3d0c5/mcontent.gif" data-lg-src="https://wol-prod-cdn.literatumonline.com/cms/attachment/c469d0ca-0c15-4544-8a60-8e9950e91ed6/mcontent.jpg">

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