A simplified synthesis of (±)-1,2-diphenyl-1,2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates "hydrobenzamide" and "amarine"
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44
摘要:
A new pathway for the simple, stereocontrolled and economical synthesis of (±)- 1 from benzaldehyde is described. The structures of two intermediates (Scheme 1) have been revised to those shown in Scheme 2.
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DOI:
10.1002/chin.199810104
被引量:
年份:
1997
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