Polymer scale preventive agent, polymerization vessel for preventing polymer scale deposition, and process of producing polymer using said vessel
申请(专利)号:
CA19912050880
申请日期:
1991-09-06
公开/公告号:
CA2050880A1
公开/公告日期:
1992-03-08
申请(专利权)人:
SHIN-ETSU CHEMICAL CO., LTD.
被引量:
摘要:
A process and coated vessel for use in the prevention of scale adhesion during the polymerization of a monomer having an ethylenic double bond, the two part coating comprising an N-substituted leucophenothiazine dye having the general formula (I): wherein Z is a carbonyl group or a sulfonyl group, R.sup.1, R.sup.2 and R.sup.3 are a hydrogen atom, alkyl group, an amino group, etc., used in conjunction with a vinyl pyrrolidone polymer. The two part coating is used on the inner wall, etc. of a polymerization vessel. Deposition of polymer scale can be effectively prevented, and polymeric product with high whiteness is obtained.
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