Synthesis, Properties, and Crystal Structure of Silyl Nitronates (Silyl Esters of aci‐Nitroalkanes): Towards the SN2 Reaction Path with Retention of Configuration at Silicon
摘要：
An efficient and flexible method for the preparation of silyl nitronates is described (see 1–10 ). NMR. spectral investigations indicate a rapid 1,3-silyl migration process, with an activation energy of about 10 kcal mol 1 . X-ray crystallographic studies on the silyl nitronates 3 and 8 show structures that lean towards an S N 2 retention pathway at silicon.
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DOI：
10.1002/hlca.19800630320
被引量：
年份：
1980
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