How Important is Parity Violation for Molecular and Biomolecular Chirality?

阅读量:

45

作者:

M Quack

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摘要:

Parity violation leads to energy differences ΔpvH=NAΔpvE of enantiomers in the femtojoule to picojoule per mole range. Recently introduced methods of electroweak quantum chemistry predict such energy differences to be one to two orders of magnitude larger than previously accepted—but still very small. How can such small energies be measured and what are the consequences for our understanding of molecular chirality, biomolecular homochirality, and perhaps fundamental physics? The review gives some tentative answers to these questions. We discuss the current status of theory and some of the current experimental approaches.

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DOI:

10.1002/anie.200290005

被引量:

513

年份:

2002

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2010
被引量:81

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