ChemInform Abstract: Synthesis and Reactions of N‐Chloromethyl‐1,2,4‐triazoles with Sulfur and Oxygen Nucleophiles
摘要：
2-Chloromethyl-1,2,4-triazole-3-thione derivatives (1 and 2) were synthesized through the hydroxy-methyl derivatives, and reacted with alkyl, aryl and heteroaryl thiols to give the corresponding sulfides (315). Compounds 1 and 2 were reacted with sodium alkoxides and phenoxide affording the corresponding ethers (1924). Transformation of CS to CO has been achieved by the action of mercuric acetate. Condensation of compounds 1 and 2 with hydrazine, phenylhydrazine and hydroxylamine yielded bicyclic condensation products 2732. Activity of the newly synthesized compounds against different kinds of fungi has been investigated in vitro.
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DOI：
10.1002/chin.199306168
被引量：
年份：
1993
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