O-silyl-substituted enols
摘要：
Although sodium bis(trimethylsilyl)amide reacts with non-enolisable carbonyl compounds to yield silyl-substituted imines and sodium silanolate, carbonyl compounds with active hydrogen are easily enolised and react differently, yielding bis(trimethylsilyl)amine and a sodium derivative of the carbonyl compound. The reaction of the resulting sodium enolates with halosilanes yields O-silyl-substituted enols, the structures of which have been proven by NMR and IR spectroscopy.
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DOI：
10.1016/S0022-328X(00)94483-8
被引量：
年份：
1964
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