NHC-containing chiral bidentate ligands: Synthesis and evaluation in enantioselective copper-catalyzed conjugate addition
摘要：
New chiral phosphine-, thiolate-, mesylate-, and tosylate-containing N -heterocyclic carbene ligands have been synthesized in fair to excellent yield. These bidentate ligands have been evaluated in enantioselective copper-catalyzed conjugate addition to both cyclic and acyclic enones and displayed good catalytic activities and poor to good enantiomeric excesses (up to 80%). Chirality, 2007. © 2007 Wiley-Liss, Inc.
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关键词：
bidentate chiral ligands N-heterocyclic carbenes asymmetric catalysis conjugate-addition copper-catalyzed
DOI：
10.1002/chir.20403
被引量：
年份：
2010
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