Selective carbon–carbon bond formations with alkenylzirconocenes
摘要:
Recent progress in the preparation of alkenylzirconocenes, the transmetalation of zirconium to zinc, palladium, and rhodium, and lithium carbenoid insertions via the 1,2-metalate rearrangement are reviewed. In addition, the regioselective alkylzirconation of alkynes and Zr-promoted cyclizations of diynes are discussed.
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DOI:
10.1016/j.tet.2003.12.018
被引量:
年份:
2004
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