ChemInform Abstract: A NOVEL PARTIALLY OXIDIZED DISTORTED ONE‐DIMENSIONAL PLATINUM CHAIN IN K1.6PT(C2O4)2.1.2H2O
摘要:
The oxidation of potassium tetracyanoplatinate(II) in the absence of halide ions results in the formation of bronze needles of K/sub 1.75/Pt(CN) . 1.5HO stoichiometry. The structure of this partially oxidized material consists of parallel one-dimensional noncollinear chains involving a commensurate repeat unit of 11.865 A. Thus the unit cell contents as deduced from single crystal x-ray data...
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DOI:
10.1002/chin.197709333
被引量:
年份:
1977
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1977
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