Method of preparing an organosilicon compound containing a methacryloxy functional group
申请(专利)号:
US20010994449
申请日期:
2001-11-28
公开/公告号:
US2002115878A1
公开/公告日期:
2002-08-22
申请(专利权)人:
WAKITA KEIJI;SHIRAHATA AKIHIKO
被引量:
摘要:
A method of preparing an organosilicon compound containing an acryloxy-functional group or a methacryloxy-functional group represented by general formula CH═CR—COO—R—Si(OR)R, where R, R, R, Rare as described below, comprising reacting (a) an alkali-metal salt of acrylic acid or an alkali-metal salt of methacrylic acid described by general formula CH═CRCOOM, where Ris a methyl group or a hydrogen atom and Mis an alkali metal and (b) an organosilicon containing a halogen-substituted organic group described by general formula XRSi(OR)R, where X is a halogen atom, Ris an alkylenoxyalkylene group or an alkylene group comprising 1 to 6 carbon atoms, R3 is an alkyl group comprising 1 to 6 carbon atoms or an alkoxyalkyl group comprising 2 to 4 carbon atoms, Ris a monovalent hydrocarbon group, and n is an integer of 1 to 3; in the presence of (c) a tertiary amine having a cyclic structure selected from the group consisting of 1,8-diazabicyclo[5.4.0]undec-7-ene, 1,4-diazabicyclo[2.2.2]octane, and 1,5-diazabicyclo[4.3.0]-non-5-ene.
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