Diastereoselective reductive imino-aldol reaction of alpha-imino esters promoted by titanium tetraiodide: synthesis of alpha,beta-diamino esters.
摘要：
Under the influence of titanium tetraiodide reductive imino-aldol reaction of theN-tosylimine derived from ethyl glyoxylate proceeded with aldimines to give α,β-diamino esters in good yields in a highly diastereoselective manner.
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关键词：
REFORMATSKY-TYPE REACTION STEREOSELECTIVE-SYNTHESIS CARBONYL-COMPOUNDS ENOLATE FORMATION AMINO 1 2-DIAMINES DERIVATIVES ALDEHYDES HALOKETONES AZIRIDINES
DOI：
10.1039/b505335h
被引量：
年份：
2005
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