Organocatalytic Enantioselective Henry Reactions
摘要：
A large number of interesting organocatalytic enantioselective protocols have been explored and successfully applied in the last decade. Among them, the Henry (nitroaldol) reaction represents a powerful carbon-carbon bond-forming procedure for the preparation of valuable synthetic intermediates, such as enantioenriched nitro alcohols, which can be further transformed in a number of important nitrogen and oxygen-containing compounds. This area of research is still in expansion and a more complex version of this useful process has recently emerged, the domino Michael/Henry protocol, affording highly functionalized cycles with multiple stereogenic centers.
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关键词：
Asymmetric catalysis Nucleophilic addition Enantioselectivity Aza‐Henry reactions Nitro‐Mannich reactions
DOI：
10.1002/ejoc.200801097
被引量：
年份：
2011
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