From Anthracene Photodimerization To Jaw Photochromic Materials And Photocrowns
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35
摘要：
The inter and intramolecular photochemical reactions of anthracenes in the absence of oxygen is discussed. The intermolecular photodimerization of 9-substituted anthracenes in fluid solution usually leads to head-to-tail photodimers; it will be shown that this trend can be obviated by non bonding attractive interactions between substituents or by mixed photodimerization. The mechanistic aspects will be examined, next, in connection with the problem of excimer intermediacy. Bis-9-anthracenes can form photocyclomers and, in certain cases, intramolecularexcimers at room temperature. Those which display interesting photochromic properties, were called "jaw compounds"; some of them induce an unusual anthracene ring cyclomerization. A study of photophysical and photochemical processes by steady state and transient kinetic analysis of α, ω-bis-9-anthryl-n-alkanes (ethane to decane) and α, ω,-bis-9-anthryl-polyoxaalkanes allows a deeper insight into the mechanism of photodimerization. By irradiation, the latter derivatives can generate "photocrowns"; this is the first photochemical synthesis of crown-ethers.
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DOI：
10.1351/pac198052122633
被引量：
年份：
1980
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