Ultraviolet photoelectron spectra of mass-selected copper clusters: Evolution of the 3 d band

来自 APS

阅读量:

55

作者:

O CheshnovskyKJ TaylorJ ConceicaoRE Smalley

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摘要:

Ultraviolet photoelectron spectra (UPS) have been measured for bare unsupported copper clusters in the 1–410 atom size range as mass selected from a supersonic, negatively charged, cluster ion beam. Using an F 2 excimer laser at 7.9 eV, the UPS patterns display the evolution of the 3 d band structure as a function of cluster size. Clusters larger than a few atoms were found to display an increasingly sharp feature at the onset of the 3 d band similar to that seen for bulk copper UPS at low photon energies, suggesting that these larger clusters may already be crystalline.

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DOI:

http://dx.doi.org/10.1103/PhysRevLett.64.1785

被引量:

404

年份:

1990

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来源期刊

Phys.rev.lett
1990-04-09

引用走势

1991
被引量:36

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