摘要：

This review covers the synthesis of isolabile vinylmetalloids through hydroboration, hydrosilylation, and hydrostannation, with special focus on recent developments, metal-catalyzed reactions, and synthetically useful methods. 1 Introduction2 Mechanistic Aspects of Hydrometallation2.1 Hydroboration2.2 Hydrosilylation2.3 Hydrostannation3 Terminal Alkynes3.1 Hydroboration of Terminal Alkynes3.2 Hydrosilylation of Terminal Alkynes3.3 Hydrostannation of Terminal Alkynes4 Internal Alkynes4.1 Hydroboration of Internal Alkynes4.2 Hydrosilylation of Internal Alkynes4.3 Hydrostannation of Internal Alkynes5 Conclusion 1 Introduction 2 Mechanistic Aspects of Hydrometallation 2.1 Hydroboration 2.2 Hydrosilylation 2.3 Hydrostannation 3 Terminal Alkynes 3.1 Hydroboration of Terminal Alkynes 3.2 Hydrosilylation of Terminal Alkynes 3.3 Hydrostannation of Terminal Alkynes 4 Internal Alkynes 4.1 Hydroboration of Internal Alkynes 4.2 Hydrosilylation of Internal Alkynes 4.3 Hydrostannation of Internal Alkynes 5 Conclusion

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