Molybdenum-Catalyzed Asymmetric Allylation of 3-Alkyloxindoles: Application to the Formal Total Synthesis of (-)-Physostigmine.
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The article investigates the molybdenum-catalyzed asymmetric allylation of 3-alkyloxindoles. The author have developed the first enantioselective mocatalyzed aymmetric allylic alkylation reaction for the 3-position of 3-alkyl oxindoles. Furthermore, the result is successful with a variety of alkyl substitutions.
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年份:
2006
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2007
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