Enantioselective Michael reaction of malonates to nitroolefins catalyzed by bifunctional organocatalysts.
摘要：
Michael reaction of malonates to nitroolefins with chiral bifunctional organocatalysts, bearing both a thiourea and tertiary amino group, afforded Michael adducts with high yields and enantioselectivities (up to 95%, up to 93% ee).
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关键词：
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism addition reactions catalysis, phase‐transfer catalysis
DOI：
10.1002/chin.200407040
被引量：
年份：
2004
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来源期刊
Cheminform
2004/02/17
引用走势
2010
被引量：302
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