Quantitative analyses of biochemical kinetic resolutions of enantiomers

Equations and useful graphs for the quantitative treatment of biochemical kinetic resolution data have been developed. These expressions have been verified experimentally, and they possess predictive values in relating the parameters of ...

C.-S. Chen，Y Fujimoto，G Girdaukas，... - 《Journal of the American Chemical Society》

Enzymatic catalysis in organic media at 100 degrees C

Porcine pancreatic lipase catalyzes the transesterification reaction between tributyrin and various primary and secondary alcohols in a 99 percent organic ...

A Zaks，A Klibanov - 《Science》

Microbial degradation of the phytosterol side chain. I. Enzymic conversion of 3-oxo-24-ethylcholest-4-en-26-oic acid into 3-oxochol-4-en-24-oic acid and androst-4-ene-3,17-dione

Porcine pancreatic lipase catalyzes the transesterification reaction between tributyrin and various primary and secondary alcohols in a 99 percent organic ...

Y Fujimoto，CS Chen，Z Szeleczky，... - 《Journal of the American Chemical Society》

Biocatalysis in water-Organic solvent two-Phase systems

The use of biphasic systems consisting of water and a water-immiscible organic solvent offers a number of advantages for the bioconversion of water-insoluble reactants. Hydrolytic enzymes can also be used in such systems to synthesize pe...

G Carrea - 《Trends in Biotechnology》

Stereoselective synthesis of optically active forms of δ-multistriatin, the attractant for european populations of the smaller european elm bark beet

A stereoselective synthesis of highly optically pure enantiomers of δ-multistriatin [(1 S,2 S,4 S,5 R)-2,4-dimethyl-5-ethyl-6, 8-dioxabicyclo[3.2.1)octane...

K Mori，H Iwasawa - 《Tetrahedron》

Enzymatic synthesis in biphasic aqueous-organic systems. II. Shift of ionic equilibria.

Ionic equilibria in 'water-water-immiscible organic solvent' systems have been studied. It has been shown that in such systems shift of the apparent p K va...

K Martinek，AN Semenov - 《Biochim Biophys Acta》

A new cubic-space section model for predicting the specificity of horse liver alcohol dehydrogenase-catalyzed oxidoreductions

A new active site model for predicting and interpreting the structural- and stereospecificity of horse liver alcohol dehydrogenase-catalyzed oxidations and reductions has been formulated from the specificity, X-ray, and kinetic data now ...

Jones，J.，Bryan，... - 《Canadian Journal of Chemistry》

Continuous Synthesis of Glycerides by Lipase in a Microporous Membrane Bioreactor

A membrane bioreactor was developed for continuous synthesis of glycerides by lipase to overcome the drawbacks associated with the usual operation in an emulsion system. One unit (total area: 726 cm 2 ) of flat, plate-type dialyzer was u...

T Yamané，MM Hoq，S Shimizu，... - 《Annals of the New York Academy of Sciences》

ChemInform Abstract: PREPARATIVE BIOORGANIC CHEMISTRY. I. SYNTHESIS OF OPTICALLY ACTIVE ALKYNYL ALCOHOLS AND α〩YDROXY ESTERS BY MICROBIAL ASYMMETRIC HYDR...

No abstract is available for this article.

K Mori，H Akao - 《Cheminform》

Continuous synthesis of glycerides by lipase in a microporous membrane bioreactor

A membrane bioreactor was developed for continuous synthesis of glycerides by lipase to overcome the drawbacks associatedwith the usual operation in an emu...

MM Hoo，T Yamane，S Shimizu，... - 《Journal of the American Oil Chemists Society》