Isolation of a New Alkaloid (-)-0- Acetylbaptifoline and the Absolute Stereochemical Relationships of Lupine Alkaloids in Thermopsis chinensis
摘要:
A new lupine alkaloid, (-)-O-acetylbaptifoline [3], was isolated from the roots of Thermopsis chinensis together with seven known (-)-anagyrine-type (7R, 9R, 11R) alkaloids. The structure of 3 was confirmed by spectroscopic methods and by chemical transformations. We also isolated (+)-lupanine [9] and (-)-sparteine [10] (6R, 7S, 9S, 11S) from this plant. These results indicate that T. chinensis has the biosynthetic ability to biosynthesize both (7R, 9R, 11R) and (7S, 9S, 11S) alkaloids.
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DOI:
10.1021/np50065a019
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年份:
2004
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