Synthesis and Coordinating Properties of New Chromone Thiosemicarbazones Towards Some Transition Metal Ions
摘要:
Copper(II), iron(III), cobalt(II,III), nickel(II), chromium(III), palladium(II), platinum(IV) and zinc(II) complexes of 2methyl7hydroxy5methoxy6formyl chromone thiosemicarbazone (H2L1), 2methyl5,7dimethoxy6formyl chromone thiosemicarbazone (HL2) have been prepared and characterized by conductance, magnetic, electronic, infrared and 1H NMR spectroscopic measurements as well as elemental and thermogravimetrical analyses. Octahedral structures are proposed for the Pt(IV), Fe(III), Co(II), Co(III), and Cr(III) complexes, whereas squareplanar configurations are suggested for the Pd(II)and Cu(II) complexes. Moreover, spectral studies indicate that the H2L1Ni complex is squareplanar and the H2L1Zn(II) complex is tetrahedral.
展开
DOI:
10.1081/SIM-120025446
被引量:
年份:
2003
通过文献互助平台发起求助,成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用!