ChemInform Abstract: HIGHLY SELECTIVE, KINETICALLY CONTROLLED ENOLATE FORMATION USING LITHIUM DIALKYLAMIDES IN THE PRESENCE OF TRIMETHYLCHLOROSILANE
摘要：
The deprotonation of ketones and esters with lithium dialkylamides in the presence of trimethylchlorosilane leads to enhanced selectivity for the kinetically generated enolate. Lithium t-octyl- t-butylamide is shown to be superior to lithium diisopropylamide in the regio-selective generation of enolates and in the stereoselective formation of E enolates.
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DOI：
10.1002/chin.198421243
被引量：
年份：
1984
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来源期刊
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2010
被引量：171
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