A highly active homogeneous ICAR ATRP of methyl methacrylate using ppm levels of organocopper catalyst
摘要：
A highly active homogeneous bulk initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) of MMA using ppm levels of organocopper catalyst Cu(SC(S)N(C<sub>4</sub>H<sub>9</sub>)<sub>2</sub>)<sub>2</sub> or Cu(SeC(Se)N(C<sub>4</sub>H<sub>9</sub>)<sub>2</sub>)<sub>2</sub> was carried out successfully for the first time. For example, even though the catalyst concentration was decreased to 1.9 ppm, the polymerization with the molar ratio of [MMA]<sub>0</sub>
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关键词：
TRANSFER RADICAL POLYMERIZATION ELECTRON-TRANSFER GLUTATHIONE-PEROXIDASE CUPROUS N N-DIETHYLDITHIOCARBAMATE INITIATING SYSTEM BLOCK-COPOLYMERS VINYL MONOMERS IRON CATALYST
DOI：
10.1039/C3PY00309D
被引量：
年份：
2013
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