Catalytic Methods for CH Bond Functionalization: Application in Organic Synthesis
摘要：
The development of catalytic reactions involving carbon-hydrogen bond cleavage is currently one of the most attractive research subjects in organic and organometallic chemistry. About 40 years have past since the pioneering report of the cleavage of C H bonds with transition metal complexes. Since that time, a vast number of studies of the cleavage of C H bonds, using stoichiometric amounts of transition metal complexes has appeared. In the last decade, a variety of catalytic reactions involving C H bond cleavage has been reported. In this review we briefly survey the results of these research activities with respect to the catalytic use of unreactive C H bonds in organic synthesis.
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关键词：
alkenylation alkylation borylation carbonylation CC bond formation CH activation silylation transition metal catalysts
DOI：
10.1002/adsc.200303094
被引量：
年份：
2003
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