Large nonlinear effect observed in the enantiomeric excess of proline in solution and that in the solid state.
摘要：
Chemical Equation Presented) A clue to the origin of chirality? A solution of proline with high enantiomeric excess (85-99% ee) was obtained from solid proline of only 10% ee through novel dissolution and crystallization processes (see scheme). This observation may be an explanation for the origin of chirality on Earth.
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DOI：
10.1002/ange.200601506
被引量：
年份：
2006
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