聚[(S)-3-(4-乙烯基苄氧基)-2,2'-二羟基-1,1'-联萘]在二乙基锌和芳基醛的不对称加成反应中的诱导
摘要:
-3-(4-vinylbenzyloxy)-2,2'-dihydroxy-1,1'-binaphthyl] (poly-) was synthesized via radical polymerization and its asymmetric inducement in the addition of diethylzinc to aromatic aldehydes was studied. The addition products have good enantioselectivity with up to 89% enantiomeric excess (). Poly- can be easily recovered and reused without loss of catalytic activity.
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DOI:
10.6023/cjoc201502011
被引量:
年份:
2015
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