Enzyme reactions in apolar solvents. The resolution of branched and unbranched 2-alkanols by porcine pancreatic lipase.
摘要:
Straight-chain and branched 2-alkanols were subjected to enzyme catalyzed transesterification in organic solvent using porcine pancreatic lipase, high enantioselectivity being generally observed. The method was applied to the synthesis of (R)-(−)-9-hydroxy-(E)-decenoic acid, a component of the queen bee mandibular gland pheromone.
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DOI:
10.1016/S0040-4020(01)96905-4
被引量:
年份:
1991
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