Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle
摘要：
Round and round it goes: Propargylic esters are versatile substrates for Au‐based catalysts. However, under typical conditions the starting Au‐coordinated propargylic ester 1 is in rapid equilibrium with the gold vinylic carbenoid species 2 and with gold allene species 3. A number of factors dictate which intermediate is lower in energy and which type of products form.
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DOI：
10.1002/anie.200703769
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年份：
2007
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